This post about us comes from
Indonesia. Quite interesting. The podcast (mp3) is in English.
Salah satu pabrik anoda baterai pertama di Eropa, di Lulea, Swedia utara, telah mulai memasok sampel produksi kepada pembuat mobil. Pabrik ini, dimiliki oleh Talga
translated from Indonesian:
News Blog
ECONOMY
8th March '23
Company seeks more environmentally friendly graphite supplies for EV batteries | 31left
D though there may be bumps in the road ahead, caused by a faltering economy and component shortages, more than 13 million electric passenger cars or plug-in hybrids are likely to be sold this year, according to Bloomberg NEF . This will take the number of EVs on world roads from 27m to just over 40m. But that's still only about 3% of the planet's vehicle fleet. With another 97% remaining, the electrification of mass transportation means there will be a huge demand for batteries and the materials they are made from.
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https://www.economist.com/media-assets/audio/074%20Science%20and%20technology%20-%20Electric%20cars-b2ce574aff2d445b1980b25511039a8f.mp3
Automakers are already worried about soaring prices and limited supplies of lithium, the critical ingredient of lithium-ion batteries at the heart of this revolution. They are also concerned about the cobalt and other materials used to make the cathode, the positive electrode inside those batteries (although the recent discovery of new reserves has allayed those concerns as they are particularly associated with cobalt). However, it takes two to tango. For each cathode, the battery needs an anode, a negative electrode. The anode is made of graphite, and a supply shock for that material is being constructed.
Graphite is a form of carbon in which the atoms are arranged in sheets. Among other things, those are things that are used as “lead” in pencils—not the highest tech applications. As such, the anode looks a bit dull compared to the cathode, with an abundant supply of raw materials to manufacture it. But, boosted by growth in EV sales, demand for graphite is set to triple from 1.2 million tonnes in 2022 to more than 4 million tonnes annually by 2030, according to Benchmark Mineral Intelligence, an analyst firm in London. Currently, supply is growing at only about two-thirds of that rate. So there may not be enough graphite for spinning, especially since this material has other large users, such as the steel industry.
Graphite used in batteries comes in two forms, both of which have their pros and cons. One is natural, dug from the ground—though the mines that yield the best value are few and far between. Others are synthetic, derived from the roasting of so-called needle coke, a by-product made in some coal and petrochemical processing plants. This roasting is an energy-intensive process that results in high emission levels. Currently, most graphite for anodes is made this way, but automakers concerned about their eco-friendly credentials are expected to increasingly seek cleaner variations of the mineral, said Benchmark's Andrew Miller.
Dig deep
Regardless of the origin, graphite must be purified to a level of 99.95% or better—because even the slightest impurities interfere with the flow of lithium ions in and out. When the battery is charging, these ions are created at the cathode by removing electrons from lithium atoms. Electrons are sent to the anode via an external circuit, and ions are also sent that way via the electrolyte inside the battery. When they reach the anode, these ions are combined with electrons supplied by the external circuit and the lithium atoms are reformed. It was then spilled on layers of graphite atoms until the battery was called upon to supply power. The process is then reversed, but with electrons in the external circuit powering a device, such as an EV electric motor.
So far, graphite remains the best material available for anodes. But purifying it is a messy business. Conventionally, highly corrosive chemicals, such as hydrofluoric acid, are used to dissolve the dirt. Most of this processing is done in China. Automakers are already quite nervous about the country's grip on about 60% of the world's lithium. However, when it comes to graphite, China controls more than 90% of the supply chain.
All of this has caused a number of companies to start diversifying their supply by opening graphite mines and processing plants elsewhere, especially in America and Europe. Since these operations are often carried out in places that impose strict environmental restrictions on the industry, cleaner methods are needed. While the company is wary of leaking trade secrets, the approach they devised should help clean up the industry.
Black gold
One of Europe's first battery anode factories, in
Lulea, northern Sweden, has started supplying automakers with production samples. The plant, owned by
Talga, a company in Perth, Australia, is supplied by a graphite mine the company is developing near Vittangi, 300 km further north. The Vittani mine produces some of the highest grade graphite in the world, which means less waste material is generated. Therefore, the environmental impact can be kept small, says Mark Thompson, boss of Talga.
The Lulea mill uses a process called low temperature alkaline roasting to strip impurities from the graphite crystal structure.
This is then washed with a milder acid than hydrofluoric*. Mr Thompson says this creates less waste than conventional approaches. For bonus green points, the plant is powered by Sweden's extensive supply of renewable hydroelectric power. The company points to an independent analysis which found the combination produces 96% fewer greenhouse gas emissions than making synthetic graphite. However, Talega is working on a proprietary process to make production greener.
*That's news to me. The application is about HF...?
As is common in the industry, after graphite has been refined, it is turned into tiny balls that form a fine black powder, before being shipped to battery makers. The shape allows these particles to be packed efficiently into the anode, increasing the contact between the particles, and thus the overall conductivity. Making the anode itself is done by turning the graphite into a slurry and then coating it with strips of copper film.
Talga expects its Swedish operation to produce more than 100,000 tons of graphite anodes per year. Depending on the size and performance characteristics of an EV , the battery pack can contain around 70-90kg of graphite. Therefore, the company's annual output can be used to power more than 1 million new vehicles.
On the other side of the world, Anthony Huston, founder of Graphite One, a firm in Vancouver, Canada, is trying something similar. His company is conducting exploratory mining at the aptly named Graphite Creek, near Nome, in western Alaska (a sample of which is shown in the figure on the previous page). It is estimated to contain more than 8 million tons of the stuff, the largest deposit in the United States — a country that has, since the 1950s, imported all of its graphite.
The idea, says Mr Huston, is to ship the graphite south to a processing plant which will be built at an undetermined location in Washington state. Here it will be purified and processed, also using renewable energy. Graphite One is working with Sunrise New Energy, a Chinese anode materials company in Zibo, Shandong province, on a purification system that will gently heat graphite in the presence of a recyclable purge gas.
Nico Cuevas, the boss of a company called Urbix, was looking for a completely different way to process graphite. Urbix has built a pilot plant at its headquarters in Mesa, Arizona. It's understood to use heat and mechanical means to excite graphite flakes in such a way that the carbon layers within them are exposed, allowing the dirt to be cleaned off with less harmful chemicals.
The Urbix method is an energy efficient process that is clean enough to be performed in a location zoned for light industrial use, said Mr Cuevas. The company will use graphite from potential sources in North America, and has signed a development deal with SK Active, the South Korean battery giant. SK On already has two battery gigafactories in America, and has formed a joint venture with Ford to build three more.
Researchers are developing anodes that use other materials. Silicon and lithium-metal anodes are theoretically more efficient at storing energy, but they have problems. Silicone, in particular, swells and contracts with charging and discharging, which can damage the battery. However, small doses of these materials can be mixed into graphite to enhance its performance. Urbix says the process allows such a substance to be inserted into the core of its graphite spheres.
Another possibility is to use a different type of carbon. Stora Enso, a Finnish forest product company, assesses that it can make anode materials from lignin. It is a natural polymer that gives wood its rigidity, but is treated as a waste product when wood is processed into paper. Usually, it is burned to produce heat. Stora Enso plans to refine it into carbon powder.
Stora Enso would not elaborate on how they do this, other than to say their process involves several heat and mechanical treatments that take place at lower temperatures than those used conventionally to produce synthetic graphite. Northvolt, a Swedish battery maker, is considering using the company's materials.
Alternatives to graphite, no doubt, will continue to develop. But with that kind of investment going into gigafactories—nearly $300 billion over the past four years, according to Benchmark, and based largely on familiarity with the materials at hand—graphite looks likely to be sticking around for some time to come. With new, lower-impact mines and cleaner processes, the dark side of electric cars will soon be a little greener.
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https://31left.com/perusahaan-mencari-persediaan-grafit-yang-lebih-ramah-lingkungan-untuk-baterai-ev-31left/
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The lignin here as in my other post reminds me of the
Cyrene project on non-toxic high performance solvent in which we are a partner.